LiFePO4 and other industrial battery types compared

 

Chemistry Nominal Voltage Energy Density
(Wh/kg)

Operating
Temperature
(oC)

Cycle Life Safety Environ-mental

Cost based on
cycle-life x Wh of VRLA

LiFePO4 3.2 >120 0 ~ 60 >20001 Safe Good  0.15 ~ 0.25
(lower than VRLA)
VRLA 2.0 >35 -20 ~ 40 >200 Safe Not good  1
NiCd 1.2 >40 -20 ~ 50 >1000 Safe Bad 0.7 
NiMH 1.2 >80 -20 ~ 50 >500 Safe Good 1.2 ~ 1.4 
LiMnxNiyCozO2 3.7 >160 -20 ~ 40 >500 Better than LiCo Ok 1.5 ~ 2.0 
LiCo2 3.7 >200 -20 ~ 60 >500 Unsafe Ok 1.5 ~ 2.0
               
       VRLA life halves per 5oC rise above 25 oC  

 

 

Lithium iron phosphate batteries possess superior thermal and chemical stability which provides better safety characteristics than those of lithium-ion technology made with other cathode materials. Lithium phosphate cells are incombustible in the event of mishandling during charge or discharge, they are more stable under overcharge or short circuit conditions and they can withstand high temperatures without decomposing. When abuse does occur, the phosphate based cathode material will not burn and is not prone to thermal runaway. Phosphate chemistry also offers a longer cycle life.

Table comparing typical voltages for VRLA, NiCd, LiFePO4 cells. (Open PDF)

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